"After talking to Lucifer and Linda, Maze realizes that she is looking for more out of life and decides to head to Canada for a tricky case. Chloe however, becomes concerned when she feels that Maze is being deceived by a scheming conman. Upon further investigation, Lucifer and Chloe make a stunning realization when they find that their target may be much closer than they thought."
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- Tom Ellis as Lucifer Morningstar
- Lauren German as Chloe Decker
- Kevin Alejandro as Dan Espinoza
- D.B. Woodside as Amenadiel (credit only)
- Lesley-Ann Brandt as Mazikeen
- Tricia Helfer as Charlotte Richards (credit only)
- Aimee Garcia as Ella Lopez (credit only)
- Scarlett Estevez as Trixie Espinoza
- Rachael Harris as Linda Martin
- Chris L. McKenna as Ben Rivers
- Marco Sanchez as Lt. T. Herrera
- Erica Cerra as Athena Burns
- Cate Cohen as Joan
- Haig Sutherland as Norm
- Stephanie Bennett as Muffy
- Fraser Corbett as Sly
- Brad Kelly as Bruce
- Sebastian Lawley as teenager
- Zachary Leblanc as squirrely dude
- Andy Nez as Peter "Pete"
- Sylvesta Stuart as Arnold
- The episode title is a reference to 2005 film Mr. & Mrs. Smith
- This was one of 4 episodes filmed as part of season 2 but planned and shown as a standalone episode in season 3.
- Mazikeen's dossier at the end is labeled "Mazikeen of the Lilim"; implying that—as in the comics—Mazikeen is a child of Lilith. This is later confirmed in Orgy Pants to Work.